Phillips 66 has patented a method to enhance the catalyst life of ZSM-5 zeolite for converting light olefins into liquid transportation fuel blend stock. By treating the zeolite with an alkaline solution and binder, the modified catalyst shows increased mesopore volume, improving performance. GlobalData’s report on Phillips 66 gives a 360-degree view of the company including its patenting strategy. Buy the report here.

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According to GlobalData’s company profile on Phillips 66, Microscale biofuel reactors was a key innovation area identified from patents. Phillips 66's grant share as of January 2024 was 57%. Grant share is based on the ratio of number of grants to total number of patents.

Modified zsm-5 catalyst with longer life for olefin conversion

Source: United States Patent and Trademark Office (USPTO). Credit: Phillips 66

A recently granted patent (Publication Number: US11872544B2) discloses a modified HZSM-5 catalyst with increased mesopore volume, produced through a specific method. The process involves treating an NaZSM-5 zeolite with alkaline and acidic solutions, followed by drying and calcining to create the modified catalyst. This modified catalyst shows enhanced mesopore volume compared to untreated HZSM-5 catalysts, with mesopores ranging from 2 to 50 nm in diameter. Additionally, the modified catalyst can be formed into extrudates, improving crush resistance, attrition resistance, and mechanical strength when combined with binder materials.

Furthermore, the patent details a method for converting ethylene into larger hydrocarbons using the modified HZSM-5 catalyst extrudate. By contacting a feed stream containing ethylene with the catalyst at specific conditions, over 85% of the ethylene can be converted into products suitable as blend stock for liquid transportation fuel. The feed stream predominantly consists of olefins and alkanes with 2-3 carbon atoms, derived from the cracking of light alkanes through thermal or catalytic cracking processes. The method also includes hydrotreating the resulting products to enhance their quality as blend stock for liquid transportation fuel. Overall, the patent highlights a novel catalyst and method for efficiently converting ethylene into valuable hydrocarbon products for various industrial applications.

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GlobalData’s Patent Analytics tracks patent filings and grants from official offices around the world. Textual analysis and official patent classifications are used to group patents into key thematic areas and link them to specific companies across the world’s largest industries.